Alkyne-induced carbyne-carbyne coupling in the trinuclear bis(carbyne) iron cluster Fe3(CO)9(.mu.3-COC2H5)(.mu.3-CCH3). X-ray structures of Fe3(CO)6(.mu.-CO)2.mu.3-.eta.4[C(OC2H5)C(CH3)C(C6H5)C(C6H5)] and Fe3(CO)6(.mu.-CO)2.mu.3-.eta.4[C(CH3)C(OC2H5)C(Si(CH3)3)C(Si(CH3)3)]

Didier Nuel (1) , Francoise Dahan (2) , René Mathieu (2)

1 ISM2 - Institut des Sciences Moléculaires de Marseille
2 LCC - Laboratoire de chimie de coordination

Domaines: Catalyse; Chimie de coordination

Didier Nuel, Francoise Dahan, René Mathieu. Alkyne-induced carbyne-carbyne coupling in the trinuclear bis(carbyne) iron cluster Fe3(CO)9(.mu.3-COC2H5)(.mu.3-CCH3). X-ray structures of Fe3(CO)6(.mu.-CO)2.mu.3-.eta.4[C(OC2H5)C(CH3)C(C6H5)C(C6H5)] and Fe3(CO)6(.mu.-CO)2.mu.3-.eta.4[C(CH3)C(OC2H5)C(Si(CH3)3)C(Si(CH3)3)]. Journal of the American Chemical Society, 1985, 107 (6), pp.1658 - 1664. ⟨10.1021/ja00292a032⟩. ⟨hal-01838171⟩